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Optical and Magnetic Properties of Mn-Doped ZnS Nanoparticles Synthesized by a Hydrothermal Method

Bui, Hong Van and Nguyen, Hoang Nam and Hoang, Nam-Nhat and Truong, Thanh Trung and Pham, Van Ben (2014) Optical and Magnetic Properties of Mn-Doped ZnS Nanoparticles Synthesized by a Hydrothermal Method. IEEE Transactions on Magnetics, 50 (6). p. 2400504. ISSN 0018-9464

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Abstract

The Mn-doped ZnS nanoparticles with T2d - F4̅3m cubic structure and an average crystalline size of about 16 nm were synthesized using the hydrothermal method at 220 °C for 15 h from Zn(CH3COO)2 (0.1M), Mn(CH3COO)2 (0.01M), and Na2S2O3 (0.1 M) as the precursors. The appearance of characteristic photoemission bands of Mn2+ (3d5) ions at 390, 430, 467, and 493 nm in the photoluminescence excitation spectra while monitoring the yellow-orange band at 585 nm showed that the Mn2+ (3d10) ions substituted for Zn2+ (3d10) ions in ZnS matrix and caused the ferromagnetism of Mn-doped ZnS nanoparticles. The dependence of photoluminescence, photoluminescence excitation spectra, and magnetization curves on Mn content and the wavelength of excitation radiation were reported.

Item Type: Article
Subjects: Engineering Physics
Divisions: Faculty of Engineering Physics and Nanotechnology (FEPN)
Depositing User: Ms. Cam Le Tran Thi
Date Deposited: 07 Nov 2015 13:16
Last Modified: 07 Nov 2015 13:19
URI: http://eprints.uet.vnu.edu.vn/eprints/id/eprint/1281

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