relation: https://eprints.uet.vnu.edu.vn/eprints/id/eprint/3017/ title: Through electrode, manufacturing method thereof, and semiconductor device and manufacturing method thereof creator: Aoyagi, Masahiro creator: Bui, Thanh Tung creator: Watanabe, Naoya creator: Kato, Fumiki creator: Kikuchi, Katsuya subject: Electronics and Communications subject: Electronics and Computer Engineering description: Provided are a through electrode including an organic side-wall insulating film, capable of eliminating a barrier layer and achieving satisfactory mechanical reliability and electrical reliability and a manufacturing method thereof, and a semiconductor device and a manufacturing method thereof. According to one aspect of the present invention, a through electrode disposed in a semiconductor substrate is provided, including: a copper layer in the semiconductor substrate; and a side-wall insulating film that is disposed between the copper layer and the semiconductor substrate so as to be in contact with the copper layer and the semiconductor substrate, the side-wall insulating film being represented by the following chemical formula (1). date: 2018-05-29 type: Patent type: NonPeerReviewed identifier: US20160322282A1 (2018) Through electrode, manufacturing method thereof, and semiconductor device and manufacturing method thereof. US9984956B2. relation: https://patents.google.com/patent/US9984956B2/en relation: US9984956B2