TY - PAT ID - SisLab3017 UR - https://patents.google.com/patent/US9984956B2/en IS - US9984956B2 A1 - Aoyagi, Masahiro A1 - Bui, Thanh Tung A1 - Watanabe, Naoya A1 - Kato, Fumiki A1 - Kikuchi, Katsuya Y1 - 2018/05/29/ N2 - Provided are a through electrode including an organic side-wall insulating film, capable of eliminating a barrier layer and achieving satisfactory mechanical reliability and electrical reliability and a manufacturing method thereof, and a semiconductor device and a manufacturing method thereof. According to one aspect of the present invention, a through electrode disposed in a semiconductor substrate is provided, including: a copper layer in the semiconductor substrate; and a side-wall insulating film that is disposed between the copper layer and the semiconductor substrate so as to be in contact with the copper layer and the semiconductor substrate, the side-wall insulating film being represented by the following chemical formula (1). TI - Through electrode, manufacturing method thereof, and semiconductor device and manufacturing method thereof AV - none ER -