%A Masahiro Aoyagi %A Thanh Tung Bui %A Naoya Watanabe %A Fumiki Kato %A Katsuya Kikuchi %T Through electrode, manufacturing method thereof, and semiconductor device and manufacturing method thereof %X Provided are a through electrode including an organic side-wall insulating film, capable of eliminating a barrier layer and achieving satisfactory mechanical reliability and electrical reliability and a manufacturing method thereof, and a semiconductor device and a manufacturing method thereof. According to one aspect of the present invention, a through electrode disposed in a semiconductor substrate is provided, including: a copper layer in the semiconductor substrate; and a side-wall insulating film that is disposed between the copper layer and the semiconductor substrate so as to be in contact with the copper layer and the semiconductor substrate, the side-wall insulating film being represented by the following chemical formula (1). %D 2018 %R US9984956B2 %L SisLab3017