TY - JOUR ID - SisLab3146 UR - https://www.elsevier.com/en-xs A1 - Joe, Sung-yoon A1 - Ryu, Shinyoung A1 - Nguyen, Duc Cuong A1 - Yim, Jong Hyuk A1 - Jeong, Huiseong A1 - Ha, Na Young A1 - Ahn, Y.H. A1 - Park, Ji-Yong A1 - Lee, Soonil Y1 - 2017/01/03/ N2 - We report a 47.1% efficiency improvement resulting from the combination of device-architecture modification and inclusion of poly(3-hexylthiophene-2,5-diyl) nanowires (P3HT NWs) in bulk heterojunction (BHJ) active layers (ALs). Modelling of ellipsometry spectra shows substantial changes in inhomogeneity and optical constants of BHJ ALs with P3HT-NW inclusion. Furthermore, finite-difference time-domain simulation results based on actual device structures with inhomogeneous AL models indicate that enhanced light harvesting is a main contributing factor to efficiency improvement. On the contrary, P3HT-NW inclusion has no significant effect on charge carrier collection, other than suppressing occurrence of cul-de-sac in hole-transport pathways and unfavourable indene-C60 bisadduct domains near top anodes. PB - Elsevier B.V. JF - Organic Electronics VL - 42 SN - 1566-1199 TI - Contributions of poly(3-hexylthiophene) nanowires to alteration of vertical inhomogeneity of bulk-heterojunction active layers and improvements of light-harvesting and power-conversion efficiency of organic solar cells SP - 372 AV - public EP - 378 ER -