eprintid: 4226 rev_number: 14 eprint_status: archive userid: 333 dir: disk0/00/00/42/26 datestamp: 2020-12-11 01:38:52 lastmod: 2020-12-23 03:15:00 status_changed: 2020-12-23 03:15:00 type: article metadata_visibility: show creators_name: Bui, Dinh Tu creators_id: buidinhtu@vnu.edu.vn corp_creators: Dao Viet Thang corp_creators: Van Quang Nguyen corp_creators: Nguyen Manh Hung corp_creators: Le Thi Mai Oanh corp_creators: Nguyen Cao Khang corp_creators: Du Thi Xuan Thao corp_creators: Nguyen Van Minh title: Structural, Optical, Ferroelectric and Ferromagnetic Properties of Bi1xGdxFeO3 Materials ispublished: pub subjects: Phys subjects: isi divisions: fac_physic abstract: Bi1xGdxFeO3 (BGFO) (x = 0.00 7 0.15) materials were prepared by a sol-gel method. The effect of Gd doping on the structural, ferromagnetic, and ferroelectric properties of BiFeO3 (BFO) were analyzed using x-ray diffraction, Raman scattering, energy-dispersive x-ray spectroscopy, ferroelectric hysteresis loop and magnetic hysteresis loop measurements. All samples showed a rhombohedral structure of the perovskite type. The a and c lattice parameters decreased with Gd content, obeying Vegard’s law, from 5.583 A˚ to 5.511 A˚ , and from 13.869 A˚ to 13.741 A˚ , respectively. The optical band gap (Eg) also decreased with Gd content, from 2.02 eV to 1.60 eV at x = 0.00 to x = 0.15, respectively. The ferroelectric and ferromagnetic properties of the BGFO materials were enhanced compared with those of the pure BFO material. Maximum saturation polarization (Ps) and saturation magnetization (Ms) values of 6.88 lC/cm2 and 0.386 emu/g were obtained. We found that the optimum Gd doping content to enhance multiferroic properties of BFO material is in range from x = 0.10 to x = 0.125. The origin of ferromagnetic and ferroelectric properties of BGFO materials were also discussed. date: 2020-05-13 date_type: published publisher: buidinhtu full_text_status: none publication: Journal of Electronic Materials volume: 49 number: 7 pagerange: 4443-4449 refereed: TRUE issn: 0361-5235 funders: the Ministry of Education and Training Vietnam Grant Number B2018-MDA-02-CtrVL. citation: Bui, Dinh Tu (2020) Structural, Optical, Ferroelectric and Ferromagnetic Properties of Bi1xGdxFeO3 Materials. Journal of Electronic Materials, 49 (7). pp. 4443-4449. ISSN 0361-5235